I don't think there'd be too much difference. Assuming that your wheels are stock, they should be 8.5" wide. This provides relatively firmer lateral support to the 235/50 tire's tread, mitigating some of what it gives up to the same make and model tire in 255/45 - and a slightly firmer ride. So what I'd expect would be for the 255/45's to ride at least as well, have slightly higher ultimate grip, and have initial cornering response just a little softer than 235/50's.
FWIW, from the front or rear, a 255/45 tire mounted on an 8.5" wide wheel will measure only about 0.4" wider than a 235/50 on that same 8.5" wide wheel. That's because on 8.5" wide wheels, the 235/50 (measured on a 7.5" wide wheel) stretches out to about 245 wide while the 255/45 is measured on 8.5" wide wheels and gains nothing. The 255/45 will still have a wider tread if you can make yourself only look at that and not the widest part on the sidewalls.
My opinion about 255/45's in general (ignoring 235/50's) - 8.5" would be the choice for when ride is clearly more important than handling, use 9" or 9.5" when handling takes increasing priority.
Norm